The goals of this study are to apply exciplex method to the visualization of the fuel spray of a diesel engine and to investigate the liquid phase of fuel spray that injected at the various tips of a fuel injector. This study provides the informations for the improvement of the diesel injection system and the structures of diesel spry with the boiling of fuel droplets in combustion chamber by the exciplex method. Hexame was used as fuel for approximation to injection condition of the engine. And naphthalene and TMDP were added to the fuel for the visualization by exciplex method. Experimental injectors were 4hole, 8hole, and 1hole impinging injectors. In the injection condition of actual engine the exciplex was sufficient to catch the liquid phase signal. The spray penetration of impinging injector was small than that of actual 4 and 8hole injector but atomization was better. The upper bound of impinging injector was determined by the geometry of a cylinder head and the lower bound was determined by spray angle. On impinging injector the atomization was better at the edge of disk than at center of disk and also the mixing with environmental gas was better.