To confirm the usefulness of partial least-squares(PLS) and multiple scattering correction(MSC) method for quantitation of surfactants in [quantitative methods using FT-lR, reconsitituted mixtures of LAS, MES and ELA-9 were tested. Each mixture was dissolved in 50% EtOH, dried, and applied to the KBr cell. From the IR spectra of these mixture, the variance spectrum was obtained. After repeated calibrations for the various regios of this spectrum, we found that 1245-1130cm-1 and 1070-1010cm-1 showed the strong correlation with each component of the sample mixture: all the correlation coefficients were 1.000 and quantitative errors did not exceed 0.32%. From this result, we concluded that PLS method and MSC method are very useful and can be successfully applied to Quality control.