- $(Mg_{0.29}-yMnyFe_{0.71})_{3-}delta$O_4$ 훼라이트계의 상평형
- ㆍ 저자명
- 채정훈,유한일,강선호,강대석,유병두
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1995년|32권 3호|pp.394-402 (9 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Electrical conductivity and thermoelectric power of the ferrous ferrite system of (Mg0.29-yMnyFe0.71)3-$delta$O4 have been measured as function of the thermodynamic variables, cationic composition(y), temperature(T) and oxygen partial pressure(Po2) under thermodynamic equilibrium conditions at elevated temperatures. On the basis of the electrical properties-phase stability correlation, the stability regions of the ferrite spinel and its neighboring phases have been subsequently located in the log Po2 vs. y and log Po2 vs. 1/T planes in the ranges of 0 y 0.29, 1100 T/$^{circ}C$ 1400 and 10-14 Po2/atm 1. The stability region, Δlog Po2(y, 1/T), of the ferrite spinel single phase widens with increasing Mn-content(y) and the boundaries of each region are linear against 1/T with negative slopes.