In general, simulation and analytic method are used for real system analysis. However, or date, there has been only the theoretical works on each approach. Therefore it is required that we study on the relationship between each approaches to obtain more reliable and correct system analysis results. In this paper, using SPN(Stochasitc Petri Net) formalism, we propose the method of output prediction of the DEVS(Discrete Event system Specification) simulation. For this we suggest a transformation algorithm which transform SPN form DEVS formalism based on the event scheduling world view and a verification algorithm for it. We then show an example to apply it to the real system, such that the Grocery Store System.