Changes in transport are reflected in the accessibility of a place, which is denoted as the inherent advantageous characteristics of a place with respect to overcoming spatial friction, and affect the land use ultimately. A composite accessibility measurement scheme is developed and applied to the subway network in Seoul, which has been constructed in 1972. Changes in the transport network are reflected in the spatial structure of accessibility and affect ultimately the land use pattern. Therefore, it is of relevance to examine the changes in the spatial structure of accessibility, which allows to forecast the direction of changes in the land use pattern.