In this paper, a Novel Approach is Proposed which Identifies linear system Parameters Using a multilayer feedforward neural network trained with backpropagation algorithm. The parameters of linear system can be represented by x9t)/x(t) and x(t)/u(t). Thud, its parameters can be represented in terms of the derivative of output with respect to input of parameters can be represented in terms of the derivative of output with respect to input of trained neural network which is a function of weights and output of neurons. Mathematical representation of the proposed approach is derived, and its validity is shown by simulation results on 2-layer and 3-layer neural network.