A mixture of sterols containing ${eta}-sitosterol$ and stigmasterol (1), and sterol glycosides containing $3-O-{eta}-D-glucopyranosyl$ ${eta}-sitosterol$ and $3-O-{eta}-D-glucopyranosyl$ stigmasterol (2) were isolated from the leaves of Gynura procumbens. After acetylation of 2 with pyridine-acetic anhydride, $3-0-{eta}-D-tetra-O-acetylglucopyranosyl$ ${eta}>-sitosterol$ (3) was isolated.