A numerical study is carried out to examine the ignition and propagation process of detonation wave in SCRam-accelerator operating in superdetonative mode. The time accurate solution of Reynolds averaged Navier-Stokes equations for chemically reacting flow is obtained by using the fully implicit numerical method and the higher order upwind scheme. As a result, it is clarified that the ignition process has its origin to the hot temperature region caused by shock-boundary layer interaction at the shoulder of projectile. After the ignition, the oblique detonation wave is generated and propagates toward the inlet while constructing complex shock-shock interaction and shock-boundary layer interaction. Finally, a standing oblique detonation wave is formed at the conical ramp.