In this paper, we proposed an estimation method of a posterior probability and PDF(Probability density function) using a feed forward neural network and code books of VQ(vector quantization). In this study, We estimates a posterior probability and probability density function, which compose a new parameter with well-known Mel cepstrum and verificate the performance for the five vowels taking from syllables by NN(neural network) and PNN(probabilistic neural network). In case of new parameter, showed the best result by probabilistic neural network and recognition rates are average 83.02%.