The white leather-like playgorskite occurs as a vein in the Cretaceous sedimentary rocks in the Yeongsan area, Kyeongnam, Korea. It has been investigate by means of XRD, TEM, DTA-TG, IR and chemical analysis. The palygorskite vein is composed mostly of well-crystallized palygorskite. The wall rock of the vein is altered to smectite along both sides of the vein. According to TEM observation the palygorskite shows a fibrous habit. The sizes offibers are quite variable, ranging from 0.1 to 3.0 micron in length. From XRD data, the palygorskite has orthorhombic unit cell with a=12.726$AA$, b=17.796$AA$, c=5.1666$AA$. The chemical formula of the palygorskite was calculated as [Si7.93Al0.07](Al1.91Fe+30.11Mg1.96)Ca0.01O20(OH)4(OH2)2.