Behaviour of ultra-high pressure diesel spray and its structure in a constant-volume pressure chamber were studied with injection pressure ranging from 35 to 110MPa. Sprays were observed by using the back illumination scattering method and righ angle scattering method. The spray process mechanism were investigated with both photographs. As a result, the spray angle and air entrainment angle was larger as injection pressure and back pressure increase. It becomes clear that mean air-fuel ratio is increased by increasing the injection pressure.