In case of a high-speed D.I. diesel engine. the injected fuel spray is unavoidable that the impinging on the wall of piston cavity and in this case the geometry of piston cavity has a great influence on the atomization structure and air flow fields. In the field of combustion and in many other spray applications, there are clear evidence of correlation between spray structure and emission of pollutants. Ordinary, the combustion chamber of driving engine have unsteady turbulent flow be attendant on such as the change of temperature, velocity and pressure. So the analysis of spray behavior is difficult. In this study, a single spray was impinged on each cavity wall at indicated angle in a quiescent atmosphere at room temperature and pressure, as being the simplest case, and 3 types of piston cavity such as Dish, Toroidal and Re-entrant type was tested for analyzing the influence of cavity geometry. And hot wire probe was used for analyze non-steady flow characteristics of impinging spray, and to investigate the behavior of spray, the aspects of concentration c(t), standard deviation $sigma(t)$ and variation factor (v.f.) was measured with the lapse of time.