The purpose of this study was to investigate the effects of training and use of worked-example on chemical problem-solving learning. Schema acquisition and rule automation are the basic components of skilled problem-solving, which are dependent on appropriately focused attention and sufficient cognitive resources. Training and use of worked-example facilitate schema acquisition and rule automation, so improve problem-solving learning. The subjects of this study were 60 high school students. The average age was 17 years old. Then, they were randomly assigned to each groups and the chemical reaction problems used as experimental materials. The independent variables of this study were training and use of worked-examples and dependent variables were time for solution and the number of error. The results of this study were as follows; 1. The worked-example groups spent significantly less time on solution for acquisition problems than the conventional problem groups. 2. The long-acquisition groups spent significantly less time on solution for acquisition problems than the short-acquisition groups. 3. The modified worked-example groups did not spend significantly less time on solution for acquisition problems than the worked-example groups.