- Cyanoethyl화에 의한 제지용 섬유의 화학적 개질효과에 관한 연구
- ㆍ 저자명
- 윤세영,조병묵,오정수,Yoon. Se-Young,Jo. Byoung-Muk,Oh. Jung-Soo
- ㆍ 간행물명
- 목재공학
- ㆍ 권/호정보
- 1997년|25권 1호|pp.56-64 (9 pages)
- ㆍ 발행정보
- 한국목재공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Since there are three hydroxyl groups on each anhydroglucose ring of the cellulose, the renewable resources, we can get various functional papers by the chemical modification of cellulose. The reaction involving the introduction of the ${eta}$-cyanoethyl ($-CH_2-CH_2$-CN) group into organic substances containing reactive hydrogen atoms is known as cyanoethylation. Cellulose reacts with acrylonitrile in the presence of strong alkalis in a typical manner of primary and secondary alcohols to form cyanoethyl ethers. In cyanoethylation, important factors of reaction are temperature, concentration of the NaOH, and addition rate of acrylronitrile. FT-IR spectra of cyanoethyl group was confirmed at $2250cm^{-1}$, which corresponds the introduction of aliphatic nitrile group. Effect of cyanoethyl DS(degree of substitution) on strength properties was resulted that cyanoethylated BKP of DS 0.04 appeared to be the best choice for overall strength properties. Also, excellent thermal stability in aging characteristics was obtained.