In this paper, we have obtained information about the orientational distribution (polar and azimuthal) of the surface molecules on backward rubbed polyimide. Using the second-harmonic genration tecnique, the nonlinear susceptibility tensor components were induced. And, the orientational distribution function was estimated without a prior assumptions, using the maximum entropy method. The polar angle of surface molecules befor rubbing is isotropic. The polar angle of surface molecules after rubbing is anisotropic along the rubbing direction. The polar angle of surface molecules after several rubbing is determined by the last rubbing direction.