- 활성탄 촉매를 이용한 CFC-113의 분해특성에 관한 연구
- A Study on the Decomposition Characteristics of CFC-113 by Activated Carbon
- ㆍ 저자명
- 이우근,정주영,김진범
- ㆍ 간행물명
- 大氣保全 : 韓國大氣保全學會誌
- ㆍ 권/호정보
- 1997년|13권 4호|pp.319-325 (7 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The catalytic decomposition of CFC-113(1,1,2-trichloro-1,2,2-trifluoroethane) was studied over an activated carbon catalyst in a fixed-bed reactor at the temperature from 300 to 600$^circ$C, the space velocity (SV) of 1800 $sim 14400h^{-1}$ and the mole ratio(decomposition agent/CFC-113) of 0.25 $sim$ 5. In the absence of a decomposition agent, the decomposition efficiency of CFC-113 was low but when a decomposition agent was added to the gas stream, it was dramatically increased with the increase of temperature. In particular, in the presence of n-hexane as the decomposition agent it showed a high decomposition efficiency compared with benzene at 400$^circ$C. It was found that the decomposition activity of CFC-113 was very sensitive to reaction temperature. Thus it is expected that to raise the reaction temperature is more effective than to increase the residence time and the amount of decomposition agent. Over the activated carbon catalyst more than 99% decomposition was achieved at the reaction temperature of 600$^circ$C, SV of 7200$h^{-1}$, the mole ration $(C_6H_{14}/CFC-113)$ of 1 in this study.