- 소결 분위기에 따른 이산화 우라늄의 치밀화 및 입자성장
- ㆍ 저자명
- 이영우
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 1997년|4권 3호|pp.214-221 (8 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The densification and grain growth mechanisms of $UO_{2+x}$ in $H_2$ and in $CO_2$ have been investigated. Uranium dioxide powder compacts were sintered at 1$700^{circ}C$ in $H_2$ or at 110$0^{circ}C$ in $CO_2$ for various times from 0.5 h to 16 h. The grain size and density of the specimens were measured. From the measured data, the mechanisms of the densification and grain growth were determined by use of available kinetic equations which express the relations between densification and grain growth. In both atmospheres, it has been found that the densification was controlled by the lattice diffusion and the grain growth by the surface diffusion of atoms around pores. It appears that the surface diffusivity as well as the lattice diffusivity increase considerably with the increase in O/U ratio in the specimen.