- Ni을 첨가한 $MoSi_2$분말성형체의 소결시 치밀화거동의 관찰
- ㆍ 저자명
- 이승익
- ㆍ 간행물명
- 한국분말야금학회지
- ㆍ 권/호정보
- 1997년|4권 4호|pp.298-303 (6 pages)
- ㆍ 발행정보
- 한국분말야금학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The activated sintering behavior of $MoSi_2$ powder compacts with addition of 0.5 and 1.0 wt.%Ni during the sintering under As atmosphere was studied. The shrinkage was measured and the microstructures were observed by SEM (scanning electron microscopy) and BEI (backscattered electron image) along with the phase analysis by EDS during heating up to 155$0^{circ}C$ and holding for various time at 155$0^{circ}C$. The most of shrinkage occurred upon heating and 92% of theoretical density was attained after sintering for 1 hr at 155$0^{circ}C$. However, little shrinkage ensued even for prolonged sintering over 1 hr at 155$0^{circ}C$. A liquid film formed at about 135$0^{circ}C$ along necks and grain boundaries. The polyhedral grain structure composed of $(Mo,Ni)_5Si_3$and $Ni_2Si$ across the $MoSi_2$ grain boundary developed at 155$0^{circ}C$. It was concluded that the activated sintering of $MoSi_2$ powder by Ni led to the diffusion of Si into Ni decreasing the liquidus temperature and the enhanced diffusion of Mo and Si through such a liquid phase and/or interboundary of $(Mo,Ni)_5Si_3$.