- PET 복합섬유의 고속방사에 따른 섬유구조형성과 물성(I) -LMPET/HMPET 복합의 효과-
- ㆍ 저자명
- 박종범,조현혹,Park. Jong-Beom,Jo. Hyeon-Hok
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1997년|34권 5호|pp.263-270 (8 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
High-speed melt spinning of sheath-core type bicomponent fibers was performed and the changes of fiber structure and property with increasing take-up velocity were investigated. The structure and property of bicomponent PET fibers spun in high-speed were analyzed through the density, birefringence, wide-angle X-ray diffraction, DSC, and stress-strain measurements. Two kinds of polymers, low molecular weight poly(ethylene terephthalate) (LMPET, η =0.62 dl/g) and high molecular weight poly(ethylene terephthalate) (HMPET, η =1.05 dl/g), were selected and spun in a sheath-core type at various take-up velocities of 1~5.5 km/min. In the structure formation of LMPET/HMPET bicomponent fibers caused by high-speed spinning, the molecular orientation of LMPET component was smaller than that of HMPET component. Orientation-induced crystallization of LMPET/HMPET bicomponent fibers in high-speed spinning was observed at take-up velocity about 4~5 km/min. As the spinning velocity increased, the amorphous orientation factor increased but the average loss tangent $delta$ decreased. In general, the LMPET/HMPET bicomponent fibers showed poor mechanical properties compared to that of LMPET single component fibers for high-speed spinning.