- 인가 전압이 Y-TZP의 저온열화에 미치는 영향
- ㆍ 저자명
- 장주웅,이홍림,김대준,오남식,이득용
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1997년|34권 12호|pp.1254-1260 (7 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Influence of applied electric field on the low temperature degradation of 3 mol% YaO3 stabilized tetragonal zirconia polycrystals(3Y-TZP) was investigated using X-ray diffractometry of specimens aged under the dc field of 1.1 kV/mm in silicone oil both of 12$0^{circ}C$-21$0^{circ}C$. After the aging, the tetragonal to monoclinic phase transformation was observed only on the specimen surface of 3Y-TZP faced to the anode. This indicated that the surface was overcrowded with oxygen ions as a result of diffusion of oxygen vacancies toward the cathode-sided surface. To elucidate an influence of the applying time of the electric field on the extent of the degradation of 3Y-TZP in air, specimens were aged fore 0-2 hours under the electric field in the oil bath of 12$0^{circ}C$ and then subsequently aged for 3h at 22$0^{circ}C$ in air. The longer the specimens were aged under the field, the more extensive the transformation to the monoclinic phase was on the specimen surface faced to the cathode, probably originated from a high diffusion rate of oxygen ions due to a steep oxygen vacancy concentration gradient.