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인가 전압이 Y-TZP의 저온열화에 미치는 영향
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  • 인가 전압이 Y-TZP의 저온열화에 미치는 영향
저자명
장주웅,이홍림,김대준,오남식,이득용
간행물명
요업학회지
권/호정보
1997년|34권 12호|pp.1254-1260 (7 pages)
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한국세라믹학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Influence of applied electric field on the low temperature degradation of 3 mol% YaO3 stabilized tetragonal zirconia polycrystals(3Y-TZP) was investigated using X-ray diffractometry of specimens aged under the dc field of 1.1 kV/mm in silicone oil both of 12$0^{circ}C$-21$0^{circ}C$. After the aging, the tetragonal to monoclinic phase transformation was observed only on the specimen surface of 3Y-TZP faced to the anode. This indicated that the surface was overcrowded with oxygen ions as a result of diffusion of oxygen vacancies toward the cathode-sided surface. To elucidate an influence of the applying time of the electric field on the extent of the degradation of 3Y-TZP in air, specimens were aged fore 0-2 hours under the electric field in the oil bath of 12$0^{circ}C$ and then subsequently aged for 3h at 22$0^{circ}C$ in air. The longer the specimens were aged under the field, the more extensive the transformation to the monoclinic phase was on the specimen surface faced to the cathode, probably originated from a high diffusion rate of oxygen ions due to a steep oxygen vacancy concentration gradient.