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$WS_2$ 고체 윤활제의 합성
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  • $WS_2$ 고체 윤활제의 합성
저자명
신동우,윤대현,황영주,김성진,김인섭
간행물명
윤활학회지
권/호정보
1997년|13권 4호|pp.60-65 (6 pages)
발행정보
한국윤활학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
서지반출

기타언어초록

The tungsten disulfide $(WS_2)$ solid lubricant was synthesized by two different reaction processes, i.e., the reaction between $CS_2$ gas phase and solid $WO_3$powder, and the vapour phase transport method of tungsten and sulfur in a high vacuum. The chemical and physical characteristics of synthesized $WS_2$powder were analyzed in terms of the average particle size, morphology, crystalline phase etc. in comparison with those of commercial $WS_2$powder. The solid $WO_3$ powder with the average size of 0.2 ${mu}{ extrm}{m}$ was reacted with $CS_2$gas flowed with$N_2$or 96%$N_2{ imes}4%H_2$forming gas for 36 h and 24 h at 90$0^{circ}C$ respectively. $WS_2$ crystalline phase was then formed through the intermediate phase of .$W_{20}O_{58}$ In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W:S=1:2.2. The mixture was then heat treated at 85$0^{circ}C$ for 2 weeks in vacuum. The reaction product obtained showed the average size of 12 ${mu}{ extrm}{m}$ and the hexagonal plate shape of typical solid lubricant with 2H-$WS_2$crystalline phase.