- $WS_2$ 고체 윤활제의 합성
- ㆍ 저자명
- 신동우,윤대현,황영주,김성진,김인섭
- ㆍ 간행물명
- 윤활학회지
- ㆍ 권/호정보
- 1997년|13권 4호|pp.60-65 (6 pages)
- ㆍ 발행정보
- 한국윤활학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The tungsten disulfide $(WS_2)$ solid lubricant was synthesized by two different reaction processes, i.e., the reaction between $CS_2$ gas phase and solid $WO_3$powder, and the vapour phase transport method of tungsten and sulfur in a high vacuum. The chemical and physical characteristics of synthesized $WS_2$powder were analyzed in terms of the average particle size, morphology, crystalline phase etc. in comparison with those of commercial $WS_2$powder. The solid $WO_3$ powder with the average size of 0.2 ${mu}{ extrm}{m}$ was reacted with $CS_2$gas flowed with$N_2$or 96%$N_2{ imes}4%H_2$forming gas for 36 h and 24 h at 90$0^{circ}C$ respectively. $WS_2$ crystalline phase was then formed through the intermediate phase of .$W_{20}O_{58}$ In the case of vapour phase transport method, the 3.5 wt% iodine was added as a vapour transport reagent into the composition of tungsten and sulfur powders maintaining a constant molar ratio of W:S=1:2.2. The mixture was then heat treated at 85$0^{circ}C$ for 2 weeks in vacuum. The reaction product obtained showed the average size of 12 ${mu}{ extrm}{m}$ and the hexagonal plate shape of typical solid lubricant with 2H-$WS_2$crystalline phase.