Experiments have been conducted to investigate emission characteristics of compressed natural gas fueled vehicle(CNGV) by the FTP 75 mode test. Its purification technologies were also investigated. It was found that CNGV was operated on the rich A/F condition by comparison with gasoline vehicle. The Pd catalyst was higher in methane purification performance than Pt and Pd/Pt/Rh catalysts. Up to 60% portion of the accumulative HC emissions(that contains above 80% methane) form CNGV occurs during the first phase of the FTP 75 mode. CO that is exhausted at rich conditions of the air-fuel ratio more than lean conditions should be used for the catalytic reduction of NOX, because the methane is not the effective reduction for NOX in the CNGV with 3-way catalyst system.