본 논문에서는 주상변압기 절연유의 가속열화반응을 수행하였다. 유중가스를 air bubbling 법으로 추출하여 가스크로마토크라프로 성분을 분석하였으며 가스농도는 각 가스의 추출율을 감안하여 보정하였다. 절연재료의 열화는 열분해반응과산화반응에의하여 진행되었으며 두 종류의 반응은 모두 0차반응의 특성을 보였고 탄화수소류, CO+{{{{ { CO}_{2 } }}}} 및 수소가스의 생성속도식을 얻었다. 유중가스 분석과 UV-Visible 분광광도법에 의하여 변압기내의 철심과 동코일이 열화과정에서 촉매역활을 함을 확인하였다.
In the paper, aging of insulating oil in pole transformer has been studied by performing accelerated thermal aging test. Dissolved gases were extracted by air bubbling method. Concentration of dissolved gases were modified by extraction ratio of each gases in insulating oil. Aging of insulating materials were proceeded by thermal degradation and oxidation reaction. Both of the reactions followed zeroch order kinetics. Formation rate equations for hydrocarbons, carbon oxides, and hydrogen were derived. It was conformed by gas analysis and UV-Visible spectrophotometric method that iron core and copper coil in pole transformer act as catalyst during the aging process.
