Currently the problem of air pollution caused by the motor vehicle emission is of the most serious problems to be solved. Life Cycle Assessment is a process to evaluate the environmental burdens associated with a product or process by identifying and quantifying energy and materials used and wasters to the environment. This paper establishes a Life Cycle Assessment Systems which satisfies the criteria motor vehicle emission for the automobile producers who are currently producing the automobiles with catalytic convert. This plan also considered the constraint of the effective motor vehicle emission by way of the exhaust gas recirculation, electronic fuel injection, closed loop carburetor. In order to develope the performance of the LCA systems, the recent emissions test data have also been applied. The result of the development LCA systems has proved that the LCA plans presented in this paper satisfies the criteria motor vehicle emission and will be contributed to constrain the motor vehicle emission most effectively.