Stream water and precipitates were analyzed for metal contents to evaluate the compositional changes of effluent water from mine waste Danbung mine located in the vicinity of Munkyung. Samples were collected before and after the rainy season in 1995 and before the rainy season in 1997 to observe seasonal variation and the charge of the status of pollution after the lapse of two years. Increased metal contents and lowered pH values after rainy season are thought of the results of flushing of oxidation products of pyrite accumulated during dry season in mine wastes. The results of two years later showed that pollution by AMD have progressed more seriously in that pH has been lowered by one order and metal contents increased about twice. The spatial distribution of various Fe, Al hydroxides and sulfates occurring as red and white precipitates also changed. Red precipitates occurred at stream bed in longer distance after two years and white precipitates occurred far down from the mine wastes where no precipitates had been observed 1995. And metal contents in sediments also increased up to more than ten times.