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디젤엔진 배출가스 저감을 위한 CO, $C_3H_6$의 산화반응에서 Y-제올라이트 담체의 영향
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  • 디젤엔진 배출가스 저감을 위한 CO, $C_3H_6$의 산화반응에서 Y-제올라이트 담체의 영향
  • Effects of Y-Zeolite as a Support on CO, $CC_3H_6$ Oxidation for Diesel Emission Control
저자명
김문찬
간행물명
大氣保全 : 韓國大氣保全學會誌
권/호정보
1997년|13권 1호|pp.91-98 (8 pages)
발행정보
한국대기환경학회
파일정보
정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Y-zeolite and ${gamma}$-Al$_2$O$_3$ were used as supports on CO and $C_3$H$_{6}$ oxidation for diesel emission control. The catalysts composed of Pd and Pt as active components were wash coated on honeycomb type ceramic substrate. The oxidation of CO and $C_3$H$_{6}$ was carried out over prepared honeycomb in a fixed bed continuous reactor in the temperature range of 20$0^{circ}C$~50$0^{circ}C$ and 20,000 GHSV (h$^{-1}$ ). Surface area of Y-zeolite was larger than that of ${gamma}$-Al$_2$O$_3$ due to channel structure of Y-zeolite. Therefore, high conversion of CO and $C_3$H$_{6}$ could be obtained because of good dispersion of active metals over Y-zeolite. The honeycomb used Y-zeolite as a support showed higher $C_3$H$_{6}$ conversion than that of ${gamma}$-Al$_2$O$_3$ due to better cracking and isomerization activity of Y-zeolite. PdPt catalyst showed high conversion of CO and $C_3$H$_{6}$ at low temperature region, 20$0^{circ}C$~30$0^{circ}C$, for their synergy effects. PdPt/Y-Zeolite catalyst could achieve more than 80% conversion of $C_3$H$_{6}$ at 30$0^{circ}C$. The use of Y-zeolite as a support increased CO and $C_3$H$_{6}$ conversion, and decreased SO$_2$ conversion very effectively. Y-zeolite found to have a good adaptability as a support for the diesel emission after treatment system.