Characteristics and properties of batteries applicable to the photovoltaic system are described in this paper. The use of a number of different types of batteries and designs depends on the many and varied requirements for battery power and the different environmental and electrical conditions under which they must operate. Most of the batteries used in PV systems are lead/acid batteries, though nickel/cadmium batteries are used for small applications in locations with extreme climates or where high reliability is essential such as spacecraft. The vanadium redox battery has been acknowledged as a promising energy storage system for a wide range of applications.