Among the heat/mass exchange units composing an absorption system, the absorber, where the refrigerant vapor is absorbed into the liquid solution is the one least understood. In the present study, the effects of non-absorbable gas on the absorption process of aqueous lithium bromide solution falling film inside a vertical tube were experimentally investigated. In the range of film Reynolds number of 30 ~ 195, heat and mass transfer characteristics were investigated as a function of non-absorbable gas volumetric concentration, 0.2 ~ 20%. An increase of non-absorbable gas volumetric concentration degraded the mass transfer rate dramatically in the absorption process. The reduction of mass transfer rate was significant for the addition of small amount of non-absorbable gas to the pure vapor. At film Reynolds number of 130, an increase of non-absorbable gas concentration from 0.2 to 6.0% resulted in the decrease of mass transfer rate by 36% and 20% of non-absorbable gas by 59%. However the decrease of film Nusselt number with the increase of volumetric concentration of non absorbable gas was relatively smaller than the decrease of Sherwood number. Critical film Reynolds number was identified to exist for the maximum heat and mass transfer regardless of the volumetric concentration of non-absorbable gases.