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백금-안티모니-비스머스계의 합성실험적 연구: 상관계 및 광물학적 의의
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  • 백금-안티모니-비스머스계의 합성실험적 연구: 상관계 및 광물학적 의의
  • Synthetic Experiment on the Pt-Sb-Bi System: Phase Equilibria and Mineralogical Significance
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김원사
간행물명
韓國鑛物學會誌
권/호정보
1998년|11권 2호|pp.117-125 (9 pages)
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한국광물학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Crystallization behavior of platinum minerals within Pt-Sb-Bi bearing ore magmas and mineralogical properties of the existing minerals were investigated at 1,00$0^{circ}C$ by synthetic experiment. High purity reagents were used as starting materials and silica tubings as containers. Reaction products were analysed by reflecting microscopy, X-ray diffraction, electron probe microanalysis, and micro-hardness test. Stable minerals at 1,00$0^{circ}C$ are platinum, electron probe microanalysis, and micro-hardness test. Stable minerals at $1,000^{circ}C$ are platinum, stump-flite (PtSb) and geversite (PtSb2). They are in equilibrium with liquid (ore magma). Platinum contains considerable amount of Sb of 7.5 at.%, whereas Bi only up to 0.9 at.%. Pure stumpflite is hexagonal with space group P63/mmc, and unit cell parameters are a=4.1318(6), c=5.483(1)$AA$. VHN50=417(2)$AA$. Geversite has cubic structure with space group Pa3. Cell parameters are a=6.4373(2)$AA$ and Vicker hardness values VHN50=663.5 (566~766). Both stumpflite and geversite show solid solution and their end-members are Pt48.8Sb40.7-Bi10.5, and Pt33.7-Sb59.8Bi6.5, respectively. Although stumpflite (m.p. $1,043^{circ}C$) and unnamed PtBi (m.p. 7$65^{circ}C$) do not form a complete solid solution at $1,000^{circ}C$, they are known, at $600^{circ}C$, to form a continuous solid solution. Geversit (m.p. $1,226^{circ}C$) also forms complete solid solution with insizwaite (m.p. $660^{circ}C$). Unit cell dimensions of the minerals above increases with the amount of Bi substituting for Sb.