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PET 복합섬유의 고속방사에 따른 섬유구조형성과 물성(II) - HMPET/LMPET 복합의 효과 -
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  • PET 복합섬유의 고속방사에 따른 섬유구조형성과 물성(II) - HMPET/LMPET 복합의 효과 -
저자명
박종범,조현혹,Park. Jong-Beom,Jo. Hyeon-Hok
간행물명
韓國纖維工學會誌
권/호정보
1998년|35권 3호|pp.125-133 (9 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

High-speed melt spinning of sheath-core type bicomponent fibers was performed and the change of fiber structure with increasing take-up velocity was investigated. Two kinds of polymers, high molecular weight poly(ethylene terephthalate) (HMPET, [η]=1.05 dl/g) and low molecular weight poly(ethylene terephthalate) (LMPET, [η]=0.62 dl/g), were selected and two sets of sheath/core combination, HMPET/LMPET and LMPET/HMPET were studied. The structure and properties of bicomponent fibers spun with high-speed were analyzed through the density, birefringence, wide-angle X-ray diffraction, DSC, and stress-strain measurements. In high speed spinning, the HMPET component attained a higher degree of orientation than that of LMPET component, wherever it was placed in a sheath or core. The orientation-induced crystallization in HMPET/LMPET bicomponent fibers made by high-speed spinning was significantly enhanced and it amounted that of the LMPET/HMPET bicomponent fibers with take-up velocity of 4-5 km/min. The amorphous orientation factor of HMPET/LMPET bicomponent fibers were always higher than those of LMPET/HMPET bicomponent fibers. Therefore the mechanical properties of HMPET/LMPET bicomponent fibers were better than those of LMPET/HMPET bicomponent fibers.