- PET 복합섬유의 고속방사에 따른 섬유구조형성과 물성(II) - HMPET/LMPET 복합의 효과 -
- ㆍ 저자명
- 박종범,조현혹,Park. Jong-Beom,Jo. Hyeon-Hok
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1998년|35권 3호|pp.125-133 (9 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
High-speed melt spinning of sheath-core type bicomponent fibers was performed and the change of fiber structure with increasing take-up velocity was investigated. Two kinds of polymers, high molecular weight poly(ethylene terephthalate) (HMPET, [η]=1.05 dl/g) and low molecular weight poly(ethylene terephthalate) (LMPET, [η]=0.62 dl/g), were selected and two sets of sheath/core combination, HMPET/LMPET and LMPET/HMPET were studied. The structure and properties of bicomponent fibers spun with high-speed were analyzed through the density, birefringence, wide-angle X-ray diffraction, DSC, and stress-strain measurements. In high speed spinning, the HMPET component attained a higher degree of orientation than that of LMPET component, wherever it was placed in a sheath or core. The orientation-induced crystallization in HMPET/LMPET bicomponent fibers made by high-speed spinning was significantly enhanced and it amounted that of the LMPET/HMPET bicomponent fibers with take-up velocity of 4-5 km/min. The amorphous orientation factor of HMPET/LMPET bicomponent fibers were always higher than those of LMPET/HMPET bicomponent fibers. Therefore the mechanical properties of HMPET/LMPET bicomponent fibers were better than those of LMPET/HMPET bicomponent fibers.