- 새로운 고성능 방향족 폴리아미드 섬유(II) - 액정방사에 의한 고강도 고탄성 방향족 poly(4,4폴-diamino-2폴-cyanobenzanilide terephthalamide) 섬유의 제조 -
- ㆍ 저자명
- 오태진,장용석
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1998년|35권 3호|pp.182-194 (13 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
In-situ polymerized anisotropic spinning solution of poly(DACYB/TPC) was prepared by low temperature solution polymerization of DACYB and TPC in N-methyl pyrrolidone with addition of equimolar amount of $Li_2CO_3$, which was directly dry-jet wet spun to give high strength (higher than 20 g/d) and high modulus (higher than 720 g/d) aromatic polyamide fiber. Mechanical properties of the fiber was strongly dependent on the dry-jet wet spinning conditions, i.e., spinneret diameter, spin draw ratio, air gap and heat treatment conditions (temperature and tension). Poly(DACYB/TPC) fiber spun through spinning holes with diameter 0.06 mm had higher tensile property than the fiber spun with diameter 0.15 mm at the same spin draw ratio, The latter, however, had higher tensile property than the former at the identical fiber thickness. Fibers prepared by dry-jet wet spinning through the air gap of around 40 mm gave the best properties by enhancing spin draw ratio. Heat treatment (above 25$0^{circ}C$) under tension (higher than 2 g/d) improved the tensile property of poly(DACYB/TPC) fiber, particularly in tensile modulus.