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Cation Self-Diffusin and Impurity Diffusion of Mn and Zn in CoO: (I) A comparison of the Residual Activity and the Tracer Sectioning Method
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  • Cation Self-Diffusin and Impurity Diffusion of Mn and Zn in CoO: (I) A comparison of the Residual Activity and the Tracer Sectioning Method
  • Cation Self-Diffusin and Impurity Diffusion of Mn and Zn in CoO: (I) A comparison of the Residual Activity and the Tracer Sectioning Method
저자명
Lee. Jong-Ho,Martin. Manfred
간행물명
The Korean journal of ceramics
권/호정보
1998년|4권 2호|pp.90-94 (5 pages)
발행정보
한국세라믹학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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Self diffusion coefficients of $^{67}$Co and impurity diffusion coefficients of $^{51}$Mn and $^{65}$Zn in single crystalline CoO have been measured by applying different radioactive isotopes simultaneously. To compare the residual activity method and the tracer sectioning method we analyzed our tracer diffusion experiments by using both methods simultaneously. According to our experimental results, the diffusion coefficients obtained from both methods are identical within experimental error, demonstrating the relibility of our experimental procedures. The diffusion coefficients of all the isotopes obtained during these test experiments for the methodology are similar in magnitude and show similar dependences on oxygen partial pressure. These first observations indicate that impurity diffusion of Mn and Zn occur via a vacancy mechanism as known for self diffusion of cobalt.