- 확산제어 성장을 통한 Bi$_4$Ge$_3$O$_{12}$유리의 결정화 메카니즘
- ㆍ 저자명
- 이근우,임영훈,양용석
- ㆍ 간행물명
- 요업학회지
- ㆍ 권/호정보
- 1998년|35권 8호|pp.890-893 (4 pages)
- ㆍ 발행정보
- 한국세라믹학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The crystallization mechanism of {{{{ { { {Bi }_{4 }Ge }_{3 }O }_{12 } }}({{{{ { {Bi }_{2 }O }_{3) } }}:{{{{ { Ge O}_{2 } }}=2:3 glass has been studied by using the non-isoth-ermal modified Ozawa equation. XRD and DTA have been used for the measurement of structural and thermal change during the transition with the sample prepared by the twin roller melt quenching method. It is found there exists middle stage {{{{ { { {Bi }_{4 }Ge }_{3 }O }_{12 } }}({{{{ { {Bi }_{2 }O }_{3) } }}:{{{{ { Ge O}_{2 } }}=1:1) crystalline phase. The obtained activation en-ergy and Avrami parameter for BGO(1:1) crystalline phase. The obtained activation en-ergy and Averami parameter for BGO(1:1) transition are 4.47$pm$0.04 eV and near 1.5 respectively. These in-dicate the crystallization occurs through the 3 dimensional diffusion controlled growth