This paper describes athermally stimulated displacement current (TSDC) of arachidic acid(AA) and polyamic acid alkylamine salts(PAAS) Langmuir-Blodgett(LB) films, which is a precursor of polyimide(PI). The TSDC measurements of AA LB film were performed from temperature to about 11$0^{circ}C$ at a rate of 0.2$^{circ}C$/ｓ inside a vacuum chamber for a reference. And the TSDC measurements PAAS LB film were performed from room temperature to about 25$0^{circ}C$ and temperature was increased at the same rate as that of AA LB film. They show that there are TSDC peaks at about 7$0^{circ}C$ in the arachidic acid LB films, and at about 7$0^{circ}C$ and 16$0^{circ}C$ in the PAAs LB films. Results of these measurements indicate the one small peak at 7$0^{circ}C$ is resulted from a softening of the alkyl group and the large peak at 16$0^{circ}C$ is possibly due to dipole of C-O group in the PASS molecule. We have calculated the vertical component of the AA and PAAs L film out of the TSDC curves. It shows that the dipole moment of the AA LB film is about 70-mD at 7$0^{circ}C$. And the dipole moment of PAAS LB film is about 040mD at 7$0^{circ}C$ and about 200mD at 16$0^{circ}C$ in the first measurement of TSDC. In the second measurement of TSDC of PASS LB film after cooling down to room temperature, the TSDC peaks are almost disappeared.