The surface potential distribution on insulating polymers was measured by scanning of the probe of an electrostatic voltmeter. The measurements were done for two measured by scanning of the probe of an electrostatis voltmeter. The measurements were done for two cases. In the first case, it was measured on the free surface of insulating films which had been inserted between plane electodes after the removal of the upper brass disk electrode. In the second case, we measured the charging region between a circular and its opposing concentric ring electrodes after the removal of dc ramp voltage in air and nitrogen gas.