Very often, whether accidentally or intentionally set fire, according as building are elevated, varied or complicated day by day. It is of primary importance that we have a treatment of fire damaged structure. In general, strength and elasticity modulus of heated concrete are reduced. Product background of cement, sand and coarse aggregate differ from country to country, so that thermal behaviour of concrete make a difference in high temperature. To cope with demand, this paper is a study on relation to microstructure and strength reduction. In consequence of experiments, concrete exposed to high temperature are estimating the reduction of mechanical properties in comparison with microstructure characteristics which are abtained from the SEM/EDX, XRD and DSC-TG analysis of heated specimens under various temperature.