The aim of this work was to investigate the effects of pigment composition on the calendering response and structure of the coated paper. Calendering response of the coated paper was determined from the gloss values of the uncalendered and calendered coated papers, and the relationship between gloss and coating structure was discussed. The surface and cross section of the coating layer was observed using a scanning electron microscope to examine the coating structure. Coating layers were hardened in epoxy resin and polished with carbimet paper disc for preparing SEM samples. Maximum calendering response was obtained for the coated paper prepared from 80pph of clay and 20pph of ground calcium carbonate (GCC) as pigments. Photomicrographs of the surface and cross section of the coating layer show that clay tends to form dense coating structure, while GCC tends to form bulky coating layer.