The importance of soundness and safety evaluation in weld zone using by the ultrasonic wave has been recently increased rapidly because of the collapses of huge structures and safety accidents. Especially, the ultrasonic method that has been often used for a major non-destructive testing(NDT) technique in many engineering fields plays an important role as a volume test method. Hence, the defecting any defects of weld Bone in austenitic stainless steel type 304 using by ultrasonic wave and neural network is explored in this paper. In order to detect defects, a distance amplitude curve on standard scan sensitivity and preliminary scan sensitivity represented of the relation between ultrasonic probe, instrument, and materials was drawn based on a quantitative standard. Also, a total of 93％ of defect types by testing 30 defect patterns after organizing neural network system, which is learned with an accuracy of 99％, based on ultrasonic evaluation is distinguished in order to classify defects such as holes or notches in experimental results. Thus, the proposed ultrasonic wave and neural network is useful for defect detection and Ultrasonic Non-Destructive Evaluation(UNDE) of weld zone in austenitic stainless steel 304.