- 기상 화학증착법에 의해 $alpha$-Alumina 지지관 상에 제조한 Silica막의 수소투과 특성
- ㆍ 저자명
- 김성수,이재홍,서동수,박상욱,서봉국
- ㆍ 간행물명
- 한국환경과학회지
- ㆍ 권/호정보
- 1998년|7권 5호|pp.669-677 (9 pages)
- ㆍ 발행정보
- 한국환경과학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
A porous $alpha$-alumina tube of 2.5 mm O.D. and 1.9 mm I.D. was used as the support of an inorganic membrane. Macropores of the tube, about 150 nm in size, were plugged with silica formed by thermal decomposition of tetraethylorthosilicate at $600^{circ}C$. The forced cross-flow CVD method that reactant was evacuated through the porous wall of the support was very effective in plugging macropores. The H$_2$ permeance of the prepared membrane was of the order of $10^{-8}/ molㆍs^{-1}/ㆍm^{-2}/. Pa{-1}$/, while the $N_2$ permeance was below $10^{-11}/ molㆍs^{-1}/ㆍm^{-2}/ㆍPa^{-1}$/ at $600^{circ}C$. This was comparable to that of silica-modified Vycor glass whose size was 4 nm.