In this study, an experimental study was performed to investigate the breakup mechanism of vaporizing droplet. A well-controlled experimental apparatus was used to study breakup mechanisms of a monodisperse stream of drops injected into a transverse high temperature and velocity air stream. The experiments gave information$ about the microscopic structure of the liquid drop breakup process, drop breakup regimes, and drop trajectories in high temperature flow region. The breakup time, drop acceleration and wavelength of surface instability wave were measured from a high-magnification and double spark photography. The two instability theories, i.e., Kelvin-Helmholtz instability and Rayleigh-Taylor instability, were estimated by comparing the calculated data with the measurements. The results showed that the breakup time in high temperature flow condition is shortened because the surface tension is decreased by the increase of gas temperature.