Numerical analysis for the combustion flow in the combustion chamber of incineration system has been carried out in order to acquire the basic design capability of incineration system. Established mathematical model was applied to the performance prediction of the pre-designed combustion chamber of commercial plant. Especially, combustion characteristics and the variation of flow pattern have been deeply discussed in accordance with secondary air injection. Secondary air injection was effective for the turbulent mixing between air and carbon monoxide/volatile matter resulting in considerably reduced CO content at the exit. Secondary air injection was found to be one of the key design parameters because the size of recirculation zone could be changed with the variation of injection characteristics.