In order to develop a thin type ESP(Electrostatic Precipitator) for high efficient air-conditioner with low concentration of ozone generation, collecting electrode spacing should be narrower than that from Deutsch formula and minimizes discharge current in ionizer. In this paper, the effect of applied voltage on the precipitation efficiency and ozone concentration of scroll type ESP was studied. As a result, precipitation efficiency(one pass) was improved by about 30[%] from increment of collector voltage(3.5[㎸]). Precipitation efficiency was increased with increasing ionizer voltage. And after some point, the efficiency was saturated. At the point, voltage and ionizer current was 5.2[㎸] and 95$[muA]$ per meter respectively. At these applied voltage conditions, ozone concentration was saturated about 0.01[ppm] after 3 hours in 23$[m^3]$ closed room test.