In this paper, an on-line process scheme is presented for implementation of a intelligent on-line modeling of nonlinear complex system. The proposed on-line process scheme is composed of FNN-based model algorithm and PLC-based simulator, Here, an adaptive fuzzy-neural networks and HCM(Hard C-Means) clustering method are used as an intelligent identification algorithm for on-line modeling. The adaptive fuzzy-neural networks consists of two distinct modifiable sturctures such as the premise and the consequence part. The parameters of two structures are adapted by a combined hybrid learning algorithm of gradient decent method and least square method. Also we design an interface S/W between PLC(Proguammable Logic Controller) and main PC computer, and construct a monitoring and control simulator for real process system. Accordingly the on-line identification algorithm and interface S/W are used to obtain the on-line FNN model structure and to accomplish the on-line modeling. And using some I/O data gathered partly in the field(plant), computer simulation is carried out to evaluate the performance of FNN model structure generated by the on-line identification algorithm. This simulation results show that the proposed technique can produce the optimal fuzzy model with higher accuracy and feasibility than other works achieved previously.