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북부 옥천변성대에서 산출되는 반점상 근청석의 미시적 공생관계 및 결정구조 해석
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  • 북부 옥천변성대에서 산출되는 반점상 근청석의 미시적 공생관계 및 결정구조 해석
  • Fine-scale Mineral Association and Crystal Structure Refinement of Spotted Cordierite from Northern Ogcheon Metamorphic Belt
저자명
노진환,최진범,김건영
간행물명
韓國鑛物學會誌
권/호정보
1999년|12권 2호|pp.55-65 (11 pages)
발행정보
한국광물학회
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정기간행물|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Spotted cordierite occurs as the result of intrusion of Wolaksan Granite of Cretaceous age in the northern part of the Ogcheon Metamorphic Belt, forming a contact metamorphic zoning in accordance with the distance from the granite body: a cordierite-muscovite-biotite-quartz assemblage and the higher-temperature cordierite-biotite-quartz-(cummingtonite). These quartz-ubiquitous mineral assemblages identified in the cordierite spot seem to reflect Al-deficient condition of the protolith. TEM observations of textural relations between the cordierite and mica within the cordierite spot clearly reflect that cordierite was formed at the expense of micaceous matrix. A structure refinement of the poikiloblastic cordierite was performed by the Rietveld refinement method. Unit cell of the cordierite was determined to be as follows : lower-temperature type: a=17.1480(9)${AA}$, b=9.7743(6)${AA}$, c=9.3184(5)${AA}$, V=1561.9(4)${AA}$3, higher-temperature type: a=17.136(2)${AA}$, b=9.751(1)${AA}$, c=9.322(1)${AA}$, V=1557.7(4)${AA}$3. They show a remarkable difference in the unit cell dimension. The refinement results indicate that structural sites of lower-temperature cordierite are wholly occupied by appropriating ions. Compared to this, tetrahedral sites of the higher-temperature type exhibit an order/disorder ranging about 5-8% as the result of substitution between Si4+ and Al3+, except for T26 site occupied wholly by Al3+. These structural differences seem to be related to the formation temperatures of both cordierite types.