- 자동차 배기가스 정화용 Pb-only 삼원촉매의 활성특성에 관한 연구
- ㆍ 저자명
- 신병선,김상수,이길우,정명근,배재호,정석진
- ㆍ 간행물명
- 한국대기환경학회지
- ㆍ 권/호정보
- 1999년|15권 5호|pp.667-676 (10 pages)
- ㆍ 발행정보
- 한국대기환경학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
The roles of ceria on three-way catalyst is to improve the noble metal dispersion and thermal stability of support ${gamma}$-$Al_2O_3$. And, ceria has a oxygen storage capacity(OSC) under fuel rich/lean conditions to improve the operating windows of NOx, THC and CO conversion. However, ceria has weak thermal stability under high temperature due to the crystallite growth. So that, the OSC of ceria is decreased, and then the conversions of NOx, THC and CO is decreased. One way of enhancing the thermal stability and NOx, THC and CO conversion Pd-only catalyst is to improve as well as its thermal stability and oxygen storage capacity of the ceria. Especially, the appropriate mixing ratios of bulk and stabilized ceria are very important for designing principles of Pd-only three-way catalysts. In this paper, we discussed the thermal properties of stabilizedand unstabilized (bulk) ceria, and the oxygen storage capacity (OSC) of catalysts, and found the correlation between activity and the OSC of Pd-only catalysts with various different mixing ratios of bulk and stabilized ceria. Finally, we propose the design principles to improve the thermal stability of washcoated Pd-only catalysts.