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폐 PET를 이용한 고상중합시 Modeling에 의한 속도론적 고찰
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  • 폐 PET를 이용한 고상중합시 Modeling에 의한 속도론적 고찰
  • Kinetics of Solid State Polycondensation of PET by Mathematical Modeling
저자명
유영식,박준욱,송석규
간행물명
韓國纖維工學會誌
권/호정보
1999년|36권 2호|pp.117-124 (8 pages)
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한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The kinetics of solid-state-polymerization of waste PET was studied by modeling the diffusion kinetics of EG. For simplicity in modeling, the equation of diffusion was assumed to be independent of crystallization rate. Plain sheet and sphere models were evaluated to find suitable model representing the shape of waste PET particle. For each model, the diffusivities of EG at 17$0^{circ}C$, 19$0^{circ}C$ and 23$0^{circ}C$ were calculated. The activation energy of plain sheet type for the diffusivities of EG was 22.97 kcal/mol and that of sphere type was 26.17 kcal/mol. While the kinetics of each model at 17$0^{circ}C$ and 19$0^{circ}C$ showed no difference, sphere model showed a better agreement with experimental data at 23$0^{circ}C$, probably due to the increase in the diffusivity of EG with temperature. A deviation was observed between the derived equation and experimental data at 23$0^{circ}C$, probably due to the oversimplification of the derived equation by ignoring the steady-change of crystallinity during the polymerization.