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연신과 열처리에 따른 폴리(트리메틸렌 테레프탈레이트) 섬유의 동적 기계적 거동 변화
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  • 연신과 열처리에 따른 폴리(트리메틸렌 테레프탈레이트) 섬유의 동적 기계적 거동 변화
  • Dynamic Mechanical Analysis of Drawn and Annealed Poly(trimethylene terephthalate) Fiber
저자명
오필록,김갑진,김영호
간행물명
韓國纖維工學會誌
권/호정보
1999년|36권 2호|pp.132-139 (8 pages)
발행정보
한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Effects of drawing and annealing on dynamic mechanical properties of poly(trimethylene terephthalate)(PTMT) fibers were investigated. PTMT obtained via polycondensation reaction of 1,3-propanediol and terephthalic acid was spun on a pilot scale extruder at the spinning speed of 1000m/min (UDY-1) and drawn to various draw ratios. It was also spun on a laboratory scale extruder at the spinning speed of 143m/min (UDY-2) and subsequently annealed at a temperature between 6$0^{circ}C$ and 18$0^{circ}C$ for 1 hour. Dynamic mechanical properties of these PTMT fibers were studied using dynamic mechanical analyzer(DMA). It was found that the glass transition temperature ($alpha$-relaxation) of UDY-1 determined by loss modulus is about 45$^{circ}C$ and increases with increasing draw ratio. The glass transition temperature of UDY-2 was about 43$^{circ}C$ and it increased up to the annealing temperature of 10$0^{circ}C$ and then decreased. The apparent activation energy of $alpha$-relaxation of PTMT fiber was determined to be about 342~396 kJ/mol which was lower than that of crystalline unoriented PET (ca. about 520kJ/mol). This suggests that the molecular chain of PTMT has lower energy barrier than that of PET and therefore the glass transition temperature of PTMT is lower than that of PET.