- 금속 프탈로시아닌 유도체 합성에 의한 촉매기능성 소취제의 제조
- Synthesis of Metal Phtalocyanine Derivatives for Catalytic Deodorant
- ㆍ 저자명
- 조동련,최창남,김현진,김애경
- ㆍ 간행물명
- 韓國纖維工學會誌
- ㆍ 권/호정보
- 1999년|36권 12호|pp.943-948 (6 pages)
- ㆍ 발행정보
- 한국섬유공학회
- ㆍ 파일정보
- 정기간행물| PDF텍스트
- ㆍ 주제분야
- 기타
Metal phthalocyanine derivatives, Fe(III)-TCMP and Cu(I)-TCMP, were synthesized to investigate their potential use as catalytic deodorants. Their chemical structures were characterized by FT-IR and AA spectroscopy, and catalytic activities were evaluated in terms of decomposition yield of hydrogen peroxide. Although both of them had sufficient activities for a catalytic deodorant, Fe(III)-TCMP showed better result than Cu(I)-TCMP. Percentage of deodorization of Fe(III)-TCMP was investigated by measuring the rate of oxidation of 2-mercaptoethanol, a representative index material for bad smelling compounds. The percentage was dependent on the concentration of Fe(III)-TCMP and reaction temperature. It increased as concentration and temperature increased. However, the percentage was high even at low concentration and low temperature. More than 95% of 2-mercaptoethanol could be removed within 30 minutes with 2% of Fe(III)-TCMP at 2$0^{circ}C$.