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금속 프탈로시아닌 유도체 합성에 의한 촉매기능성 소취제의 제조
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  • 금속 프탈로시아닌 유도체 합성에 의한 촉매기능성 소취제의 제조
  • Synthesis of Metal Phtalocyanine Derivatives for Catalytic Deodorant
저자명
조동련,최창남,김현진,김애경
간행물명
韓國纖維工學會誌
권/호정보
1999년|36권 12호|pp.943-948 (6 pages)
발행정보
한국섬유공학회
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

Metal phthalocyanine derivatives, Fe(III)-TCMP and Cu(I)-TCMP, were synthesized to investigate their potential use as catalytic deodorants. Their chemical structures were characterized by FT-IR and AA spectroscopy, and catalytic activities were evaluated in terms of decomposition yield of hydrogen peroxide. Although both of them had sufficient activities for a catalytic deodorant, Fe(III)-TCMP showed better result than Cu(I)-TCMP. Percentage of deodorization of Fe(III)-TCMP was investigated by measuring the rate of oxidation of 2-mercaptoethanol, a representative index material for bad smelling compounds. The percentage was dependent on the concentration of Fe(III)-TCMP and reaction temperature. It increased as concentration and temperature increased. However, the percentage was high even at low concentration and low temperature. More than 95% of 2-mercaptoethanol could be removed within 30 minutes with 2% of Fe(III)-TCMP at 2$0^{circ}C$.