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Reactioin Characteristics of the Sm2Fe17-xGax(x0, 2) Alloy with Hydrogen and Methane Gas
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  • Reactioin Characteristics of the Sm2Fe17-xGax(x0, 2) Alloy with Hydrogen and Methane Gas
  • Reactioin Characteristics of the Sm2Fe17-xGax(x0, 2) Alloy with Hydrogen and Methane Gas
저자명
Shon. S.W,Kwon. H.W
간행물명
Journal of magnetics
권/호정보
1999년|4권 4호|pp.123-127 (5 pages)
발행정보
한국자기학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The Ga-stabilised $Sm_2Fe_{17-}$type alloy can hardly be disproportionated under ordinary HDDR condition. The HDDR characteristics of Ga-substituted $Sm_2Fe_{17-}$type alloy were examined, and, in particular, the effect of particle size on the disproportionation of the Ga-substituted alloy was investigated in detail. The reaction characteristics of the $Sm_2Fe_{17-}$type alloys with or without Ga-substitution with methane (CH4) gas are also examined. The Ga-stabilised $Sm_2Fe_{17-}$type alloy was able to be disproportionated significantly on heating up to 80$0^{circ}C$ under hydrogen with normal pressure. The particle size influenced significantly on the disproportion-ation of the Ga-substitute alloy, and the materials with finer particle size (<40 ${mu}{ extrm}{m}$) was fully disproportionated on heating up to around 80$0^{circ}C$ under hydrogen gas with normal pressure. The Ga-substituted alloy has a very sluggish recombination kinetics with respect to the alloy without Ga-substitution. The $Sm_2Fe_{17}C_{x-}$type carbide was stabilised significantly by the Ga-substitution for Fe in the parent alloy. While the $Sm_2Fe_{17}C_x$ was disproportionated below 80$0^{circ}C$ the Ga-stabilised $Sm_2Fe_{14}Ga_2C_x$ carbide remained intact even on heating up to 80$0^{circ}C$.