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AC Impedance Characteristics of the Corroded Hydrogen-Charged Zircaloy-4 Alloy
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  • AC Impedance Characteristics of the Corroded Hydrogen-Charged Zircaloy-4 Alloy
  • AC Impedance Characteristics of the Corroded Hydrogen-Charged Zircaloy-4 Alloy
저자명
김선재,김경호,백종혁,최병권,정용환,Kim. Seon-Jae,Kim. Gyeong-Ho,Baek. Jong-Hyeok,Choe. Byeong-Gwon,Jeong. Yong-Hwan
간행물명
한국재료학회지
권/호정보
1999년|9권 2호|pp.205-210 (6 pages)
발행정보
한국재료학회
파일정보
정기간행물|ENG|
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이 논문은 한국과학기술정보연구원과 논문 연계를 통해 무료로 제공되는 원문입니다.
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기타언어초록

The 250ppm hydrogen-charged Zircaloy-4 sheets, homogenized at $400^{circ}C$ for 72hrs in vacuum, were corroded under the autoclave conditions of $350^{circ}C$, 2350psi. The corrosion behavior of the Zircaloy-4 sheets was evaluated by measuring their weight gains with the exposure time. The electrical characteristics were investigated in the ranges of 5000~1x10ulcornerHz using AC impedance technique in 1N $H_2$$SO_4$aqueous solution. The corrosion rate of the hydrogen charged specimen was more rapid than the normal specimen at the early stage of the corrosion. With a longer corrosion time, however, the normal specimen corroded faster than the hydrogen-charged specimen. At the same time the hydrogen pickup in the hydrogen-charged specimen was more suppressed compared with the normal specimen. Such appears to be occurred because the impedance for the movement of the hydrogen ion into the metal was higher in the hydrogen-charged specimen compared to normal specimen at the interface between the oxide layer and the uncorroded metal. Thus the corrosion rate of the hydrogen-charged specimen was likely to be decreased with a longer corrosion time.